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Improving Member States preparedness to face an HNS pollution of the Marine System (HNS-MS)

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Chloroacetic Acid Solutions

Description Top

CAS number 79-11-8
UN number 3250
Chemical formula C2H3ClO2
Standard European Behaviour Classification (SEBC) Dissolves (D)
Abilities Solution.
GESAMP Hazard profile
A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
0 R 2 0 2 3 4 3C 3 A NI D 3

Marine pollution Classification (MARPOL Annex II)
Category Description
Y Noxious Liquid Substances which, if discharged into the sea from tank cleaning or deballasting operations, are deemed to present a hazard to either marine resources or human health or cause harm to amenities or other legitimate uses of the sea and therefore justify a limitation on the quality and quantity of the discharge into the marine environment.

Alternate names for this chemical
Monochloroacetic Acid
Chloroacetic Acid Solutions
Solutions D'Acide Chloroacetique


Physico-chemical properties Top

Chemical formula C2H3ClO2
State Liquid at 25°C and 1 atm
Hydrosolubility
10000000 [mg/l] at a temperature of 20°C and salinity of 0‰


Behaviour Top

Standard European Behaviour Classification (SEBC) Dissolves (D)


Hazards Top

Corrosive
Toxic
Environmental Hazard

Danger

Hazards statements
Physical
H290
May be corrosive to metals.
Health
H301
Toxic if swallowed.
H311
Toxic in contact with skin.
H314
Causes severe skin burns and eye damage.
H331
Toxic if inhaled.
H335
May cause respiratory irritation.
Environmental
H410
Very toxic to aquatic life with long lasting effects.

Precautionary statements
Prevention
P234
Keep only in original container.
P260
Do not breathe dust/fume/gas/mist/vapours/spray.
P273
Avoid release to the environment.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
Response
P390
Absorb spillage to prevent material damage.
P301 + P330 + P331
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P309 + P311
IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
Storage
P406
Store in corrosive resistant/... container with a resistant inner liner.
Disposal
P501
Dispose of contents/container to ...


GESAMP Top

GESAMP Hazard profile
A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
0 R 2 0 2 3 4 3C 3 A NI D 3

A1: Bioaccumulation
Rating Description
0 No potential to bioaccumulate
A1a:
Rating Description Criteria [mg/l]
0 No potential to bioaccumulate Log Kow < 1
A1b:
Rating Description
NI No Information
A2: Biodegradation
Rating Description
R Readily biodegradable
B1: Acute aquatic toxicity
Rating Description Criteria [mg/l]
2 Slightly toxic 10 < LC/EC/IC50 ≤ 100
B2: Chronic aquatic toxicity
Rating Description Criteria [mg/l]
0 Negligible NOEC > 1
C1: Acute oral toxicity
Rating Description Criteria [mg/Kg]
2 Moderate 50 < AOTE ≤ 300
C2: Acute dermal toxicity (skin contact)
Rating Description Criteria [mg/Kg]
3 Moderately high 50 < ADTE ≤ 200
C3: Acute inhalation toxicity
Rating Description Criteria [mg/l] (4 hours exposure)
4 High AITE ≤ 0.5
D1: Skin irritation or corrosion
Rating Description Sign GHS category
3C Corrosive Full-thickness skin ne Corrosive Category 1A
D2: Eye irritation
Rating Description Sign GHS category
3 Severely irritating or corrosive Severe conjunctoblepha Irritant Category 1
D3: Long-term health effects
Notation Hazard endpoint Description GHS category
A Aspiration Lung injury or chemical pneumonia following aspiration of a chemical through the oral or nasal cavity into the trachea or lower respiratory system Category 1 for Aspiration Toxicity
E1: Tainting of seafood
Rating Description
NI No Information
E2: Behaviour of chemicals in the marine environment
Rating Description
D Dissolves
E3: Interference with the use of coastal amenities
Rating Interference Description Interpretation Warning
3 Highly objectionable 1 is highly acutely toxic; and/or 2 is severely irritant or corrosive to skin or eyes; and/or 3 is carcinogenic, mutagenic or reprotoxic; and/or 4 is a floater or persistent floater with associated health effects 1 C1 and/or C2 and/or C3 = 4; and/or 2 D1 or D2 = 3, 3A, 3B, or 3C; and/or 3 D3 contains C, M or R; and/or 4 E2 = F or Fp and D3 contains Ss, Sr, T, A, N, or I Warning issued leading to the closure of amenities

GHS Security Information

Corrosive
Toxic
Environmental Hazard

Danger

  About the project

HNS-MS is a decision-support tool that Belgian and French maritime authorities as well as coastguard stations can activate in order to forecast the drift, fate and behavior of acute marine pollution by Harmful Noxious Substances (HNS) accidentally released in the marine system.

  Contact us

Web: https://www.hns-ms.eu/

Tel : +32 (0)2 773-2102

Mail : hns-ms@naturalsciences.be

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EU flagHNS-MS has been funded by DG-ECHO under agreement ECHO/SUB/2014/693705 and runs from 1 January 2015 to 31 March 2017.